Electrostatically Driven Large Aperture Micro-Mirror Actuator Assemblies for High Fill-Factor, Agile Optical Phase Arrays

Aircraft laser beamsteering is accomplished using a single gimbaled mirror housed inside a turret, which protrudes from the fuselage and causes unwanted turbulence, vibrations, and weight. The Air Force is currently investigating the use of microelectromechanical systems (MEMS) micro-mirror arrays to replace aircraft beamsteering technology. MEMS micro-mirror arrays provide a unique solution to address these issues. Unfortunately, current MEMS micro-mirror technology cannot meet all the beamsteering requirements in a single assembly. These include high fill-factor, large aperture, 25 degrees of out-of-plane deflection, 4-axis tilt, and actuation speeds below 1 ms. In this research, a novel MEMS actuation scheme to address all these requirements using electrostatically driven bimorph cantilever beams was designed, modeled, fabricated, and characterized. Modeling results show a linear relationship between the number of cantilever beams and maximum deflection. Characterization of fabricated micro-mirror assemblies supports the modeling for individual actuators as well as for micro-mirror platform assemblies. Fabricated devices reached vertical deflections greater than 170 micrometer with pull-in voltages of 20 V and an optical range of 16 degrees. These large deflections, low pull-in voltage, and reasonable optical range shown in this research demonstrate the feasibility of using MEMS micro-mirror arrays to address aircraft beamsteering issues

EPR and preparative studies of 5-endo cyclizations of radicals derived from alkenyl NHC-boranes bearing tert-butyl ester substituents

J.C.W. thanks EaStCHEM for financial support, and D.P.C. thanks the US National Science Foundation. Computational support was provided through the EaStCHEM Research Computing Facility.Radical H atom abstraction from a set of N-heterocyclic carbene (NHC) complexes of alkenylboranes bearing two tert-butyl ester substituents was studied by EPR spectroscopy. The initial boraallyl radical intermediates rapidly ring closed onto the O atoms of their distal ester groups in 5-endo mode to yield 1,2-oxaborole radicals. Unexpectedly, two structural varieties of these radicals were identified from their EPR spectra. These proved to be two stable rotamers, in which the carbonyl group of the tert-butyl ester was oriented toward and away from the NHC ring. These rotamers were akin to the s-trans and s-cis rotamers of α,β-unsaturated carbonyl compounds. Their stability was attributed to the quasi-allylic interaction of their unpaired electrons with the carbonyl units of their adjacent ester groups. EPR spectroscopic evidence for two rotamers of the analogous methyl ester containing NHC-oxaborole radicals was also obtained. An improved synthetic procedure for preparing rare NHC-boralactones was developed involving treatment of the alkenyl NHC-boranes with AIBN and tert-dodecanethiol.PostprintPeer reviewe

EPR studies on the addition of ligated boryl radicals to carbonyl compounds

J.C.W. thanks EaStCHEM for financial support and D.P.C. thanks the US National Science Foundation. Computational support was provided through the EaStCHEM Research Computing Facility.The boron-centered radicals derived from alkenyl N-heterocyclic carbene (NHC)-boranes bearing ester substituents were recently found to ring close in 5-endo mode by addition to the oxygen atoms of the ester substituents. The inference from this was that NHC-boryl radicals might add intermolecularly to carbonyl-containing substrates. Several different NHC-boryl radicals were generated by H-atom abstraction from NHC-ligated trihydroborates. Electron paramagnetic resonance (EPR) spectroscopy proved that these did indeed add to the oxygen atoms of diaryl ketones with production of the corresponding bora-ketyl radicals. The same unusual regioselectivity of addition was observed with monoaryl ketones, but no bora-ketyls were observed with dialkyl ketones. Similarly, no bora-ketyl adduct radicals were observed with esters, even esters of benzoic acid. EPR spectroscopic evidence suggested that NHC-boryl radicals were also added to the O-atoms of aromatic aldehydes. Amine-boryl and phosphine-boryl radicals were also observed to add to the O-atom of benzophenone with production of the corresponding ketyl radicals.PostprintPeer reviewe

First documentation of in vivo and in vitro ivermectin resistance in Sarcoptes scabiei

Ivermectin is increasingly being used to treat scabies, especially crusted (Norwegian) scabies. However, treatment failures, recrudescence, and reinfection can occur, even after multiple doses. Ivermectin resistance has been documented for some intestinal helminths in animals with intensive ivermectin exposure. Ivermectin resistance has also been induced in arthropods in laboratory experiments but, to date, has not been documented among arthropods in nature. We report clinical and in vitro evidence of ivermectin resistance in 2 patients with multiple recurrences of crusted scabies who had previously received 30 and 58 doses of ivermectin over 4 and 4.5 years, respectively. As predicted, ivermectin resistance in scabies mites can develop after intensive ivermectin us

Generation and structure of unique boriranyl radicals

J.C.W. thanks EaStCHEM for financial support. T.R.M. and D.P.C. thank the US National Science Foundation for grant CHE-1660927.Three-member ring boracyclopropanes (boriranes) with N-heterocyclic carbene substituents were prepared by a recently discovered route. H atoms were selectively abstracted from the boron atoms by t-butoxyl radicals and this enabled boriranyl radicals to be detected and characterized by EPR spectroscopy for the first time. Their EPR parameters indicated they had planar π-character. From competition experiments, the rate constant for H atom abstraction was determined and found to be about 2 orders of magnitude less than for NHC-boranes. The B–H BDE of an NHC-borirane was estimated to be about 95 kcal mol–1.PostprintPeer reviewe

Assessment of the Environmental Impact of Food Consumption in Ireland-Informing a Transition to Sustainable Diets

Dietary changes are required to mitigate the climatic impact of food consumption. Food consumption databases can support the development of sustainable food based dietary guidelines (SFBDG) when linked to environmental indicators. An improved knowledge base is crucial to the transition to sustainable diets, and multiple environmental indicators should be considered to ensure this transition is evidence based and accounts for trade-offs. The current study aimed to quantify the environmental impact of daily diets across population groups in Ireland. Nationally representative food consumption surveys for Irish children (NCFSII; 2017-2018), teenagers (NTFSII; 2019-2020), and adults (NANS; 2008-2010) were used in this analysis. Blue water use (L) and greenhouse gas emissions (GHGe; kgCO2eq) were assigned at food level to all surveys. Cropland (m2), nitrogen (kgN/t), and phosphorous use (kgP/t) were assigned at the agricultural level for adults. Multiple linear regressions, Spearman correlations, and ANCOVAs with Bonferroni corrections were conducted. Higher environmental impact diets were significantly associated with demographic factors such as age, education status, residential location, and sex, but these associations were not consistent across population groups. The median greenhouse gas emissions were 2.77, 2.93, and 4.31 kgCO2eq, and freshwater use per day was 88, 144, and 307 L for children, teenagers, and adults, respectively. The environmental impact of the Irish population exceeded the planetary boundary for GHGe by at least 148% for all population groups, however the boundary for blue water use was not exceeded. Meat and meat alternatives (27-44%); eggs, dairy, and dairy alternatives (15-21%); and starchy staples (10-20%) were the main contributors to GHGe. For blue water use, the highest contributors were meat and meat alternatives in children; savouries, snacks, nuts, and seeds in teenagers; and eggs, dairy, and dairy alternatives in adults (29-52%). In adults, cropland use, nitrogen use, and phosphorous use exceeded planetary boundaries by 277-382%. Meat, dairy, and grains were the main contributors to cropland, nitrogen, and phosphorous use (79-88%). The quantified environmental impact of Irish diets provides a baseline analysis, against which it will be possible to track progress towards sustainable diets, and the basis for the development of Sustainable Food Based Dietary Guidelines in Ireland

NuSTAR Discovery of a Cyclotron Line in the Be/X-ray Binary RX J0520.5-6932 During Outburst

We present spectral and timing analysis of NuSTAR observations of RX J0520.5$-$6932 in the 3-79 keV band collected during its outburst in January 2014. The target was observed on two epochs and we report the detection of a cyclotron resonant scattering feature with central energies of $E_\mathrm{CRSF} = 31.3_{-0.7}^{+0.8}$ keV and $31.5_{-0.6}^{+0.7}$ keV during the two observations, respectively, corresponding to a magnetic field of $B \approx 2 \times10^{12}$ G. The 3-79 keV luminosity of the system during the two epochs assuming a nominal distance of 50 kpc was $3.667\pm0.007\times 10^{38}\,\mathrm{erg\,s^{-1}}$ and $3.983\pm0.007\times10^{38}\,\mathrm{erg\,s^{-1}}$. Both values are much higher than the critical luminosity of $\approx1.5\times10^{37}\,\mathrm{erg\,s^{-1}}$ above which a radiation dominated shock front may be expected. This adds a new object to the sparse set of three systems that have a cyclotron line observed at luminosities in excess of $10^{38}\,\mathrm{erg\,s^{-1}}$. A broad ($\sigma\approx0.45$ keV) Fe emission line is observed in the spectrum at a central energy of $6.58_{-0.05}^{+0.05}$ keV in both epochs. The pulse profile of the pulsar was observed to be highly asymmetric with a sharply rising and slowly falling profile of the primary peak. We also observed minor variations in the cyclotron line energy and width as a function of the rotation phase.% As in observations of other cyclotron absorption line sources, there is a small ($\Delta\phi\lesssim0.1$) phase difference between the peak of the cyclotron energy variation and the peak of the flux variation.Comment: 9 pages, 4 figures, 6 tables. Accepted to Ap

Geotextile behavior relevant to filtering low density suspended organic particles

Presented at the 8th International Geosynthetics Conference. Yokohama, Japan.This paper describes experiments on the feasibility of using geotextiles to filter organics from runoff and combined sewer overflows. A horizontal flow permittivity test apparatus was used as a prototype to test 15cm x 20cm coupons. Non-woven, needle-punched products supported both depth (interior) and cake(surface) filtration modes. Crushed anthracite in the #100-#200 mesh range was used as an inert, replicable analogue of low density, irregularly shaped suspended particles. The AOS detected with this material differs from that measured with standard media, indicating different interaction with the geotextile pore structure.Drag forces maintained a cake on the upstream face of the filter even at low hydraulic gradients. The permittivity decreased as this coating thickened. When flow ceased, the organic cake sloughed off the upstream face of the coupon. Measurements made after several doses showed recovery of much of the original permittivity, with the loss in hydraulic capacity attributed to embedment of particles in the matrix

NuSTAR and Swift observations of the black hole candidate XTE J1908+094 during its 2013 outburst

The black hole candidate XTE J1908+094 went into outburst for the first time since 2003 in October 2013. We report on an observation with the Nuclear Spectroscopic Telescope Array (NuSTAR) and monitoring observations with Swift during the outburst. NuSTAR caught the source in the soft state: the spectra show a broad relativistic iron line, and the light curves reveal a ~40 ks flare with the count rate peaking about 40% above the non-flare level and with significant spectral variation. A model combining a multi-temperature thermal component, a power-law, and a reflection component with an iron line provides a good description of the NuSTAR spectrum. Although relativistic broadening of the iron line is observed, it is not possible to constrain the black hole spin with these data. The variability of the power-law component, which can also be modeled as a Comptonization component, is responsible for the flux and spectral change during the flare, suggesting that changes in the corona (or possibly continued jet activity) are the likely cause of the flare.Comment: 9 pages, 6 figures, 3 tables, accepted for publication in Ap